电子渠道用户发展现状浅析——以江苏省广电有线信息网络股份有限公司为例

通过对江苏省全省电子渠道用户的总量和地区分布,分析了电子渠道缴费用户的流失及消费情况,找出了目前电子渠道存在的一些问题,并提出相应的策略。     

Structure,mechanical and thermal properties of Y-doped CrAlN coatings

CrAlYN coatings with different Y contents (0, 5 and 12 at.%) were deposited by cathodic arc evaporation to investigate the influence of Y-addition on the structure, mechanical and thermal properties of CrAlN coatings by using X-ray diffraction, scanning electron microscopy, differential scanning calorimetry, thermal gravimetric analysis and nanoindentation. The structural transformation of single phase cubic Cr_0.42Al_0.58N and Cr_0.39Al_0.56Y_0.05N coatings to cubic–wurtzite mixed Cr_0.32Al_0.56Y_0.12N coating leads to a drop in hardness from (30.2±0.7) GPa of Cr_0.42Al_0.58N and (32.0±1.0) GPa of Cr_0.39Al_0.56Y_0.05N to (25.2±0.7) GPa of Cr_0.32Al_0.56Y_0.12N. The incorporation of 5 at.% Y retards the thermal decomposition of CrAlN, verified by the postponed precipitation of w-AlN and N-loss upon annealing. Correspondingly, Cr_0.39Al_0.56Y_0.05N coating consistently exhibits the highest hardness value during thermal annealing. Nevertheless, alloying with Y exerts an adverse effect on the oxidation resistance of CrAlN.     

Mesoporous SmMnO3/CuMnOx catalyst for photothermal synergistic degradation of gaseous toluene

Mesoporous SmMnO₃/CuMnO_x catalyst was prepared by a two-step method using flaky CuMnO_x with high specific surface and excellent catalytic ability as the carrier, which was further applied to photothermal synergistic degradation of gaseous toluene. Quantitative analysis of O₂-TPD and H₂-TPR showed that SmMnO₃/CuMnO_x exhibited abundant of the surface oxygen species and oxygen vacancies content, which enabled it to convert free oxygen to lattice oxygen more quickly during the reaction, and thus improving the reaction process. I-t and photoluminescence experiments demonstrated the improvement of photogenerated electron and hole separation ability of SmMnO₃/CuMnO_x catalyst. UV–Vis analysis manifested the full spectral range of absorption. XPS analysis verified the unequal positions of valence band of the two materials, which can facilitate the separation of photogenerated electrons from holes and improve the ability of better electron transfer. SmMnO₃/CuMnO_x catalyst has higher adsorbed oxygen content and light absorption capacity, which is beneficial to the catalytic oxidation. In situ DRIFTs proved that the oxidation reaction on the catalyst followed the Mars-van Krevelen redox cycle. The VOCs test found that SmMnO₃/CuMnOx composite catalyst is with lower onset reaction temperature (T₉₀ = 190 °C, T₉₀, corresponding to 90% conversion) and good mineralization (100% at 275 °C).     

Excision of Oxidatively Generated Guanine Lesions by Competitive DNA Repair Pathways

The base and nucleotide excision repair pathways (BER and NER, respectively) are two major mechanisms that remove DNA lesions formed by the reactions of genotoxic intermediates with cellular DNA. It is generally believed that small non-bulky oxidatively generated DNA base modifications are removed by BER pathways, whereas DNA helix-distorting bulky lesions derived from the attack of chemical carcinogens or UV irradiation are repaired by the NER machinery. However, existing and growing experimental evidence indicates that oxidatively generated DNA lesions can be repaired by competitive BER and NER pathways in human cell extracts and intact human cells. Here, we focus on the interplay and competition of BER and NER pathways in excising oxidatively generated guanine lesions site-specifically positioned in plasmid DNA templates constructed by a gapped-vector technology. These experiments demonstrate a significant enhancement of the NER yields in covalently closed circular DNA plasmids (relative to the same, but linearized form of the same plasmid) harboring certain oxidatively generated guanine lesions. The interplay between the BER and NER pathways that remove oxidatively generated guanine lesions are reviewed and discussed in terms of competitive binding of the BER proteins and the DNA damage-sensing NER factor XPC-RAD23B to these lesions.     

Improved formic acid oxidation using electrodeposited Pd–Cd electrocatalysts in sulfuric acid solution

In the present research, nanostructured Pd–Cd alloy electrocatalysts with different compositions were produced using the electrodeposition process. The morphology of the samples was studied by scanning electron microscopy analysis. Also, the elemental composition of the samples was determined by energy-dispersive X-ray spectroscopy and elemental mapping tests. Tafel polarization and electrochemical impedance spectroscopy methods were employed to determine the electrochemical corrosion properties of the synthesized samples in a solution containing 0.5 M sulfuric acid and 0.1 M formic acid. The linear sweep voltammetry, cyclic voltammetry, and chronoamperometry techniques were also employed to evaluate the electrocatalytic activity of prepared samples toward the oxidation of formic acid. In this respect, the influence of some factors such as formic acid and sulfuric acid concentrations and also potential scan rate was investigated. Compared to the pure Pd sample, the Pd–Cd samples were more reactive for the oxidation of formic acid. Besides, the sample with a lower amount of Pd (Pd_1·3Cd) demonstrated much higher electrocatalytic activity than the Pd_7·1Cd and Pd_2·1Cd samples. The observed high mass activity of 15.06 A mg^?1_Pd for the Pd_1·3Cd sample which is 21.1 times higher than Pd/C is an interesting result of this study.     

基于Abaqus的双裂纹不同间距对裂纹扩展速率的研究

扩展有限元法是近年经过大量运用的,在传统有限元的范围中求解不连续问题一种有效计算方法,它是基于单位分解的思想,在计算不连续问题时加入跳跃函数。以ABAQUS为平台,基于扩展有限元方法 (XFEM),以含双穿透型裂纹的有限宽板受横向拉伸载荷为力学模型,建立相应的裂纹尖端应力的有限元模型,研究焊接接头区域不同间距双裂纹相互作用对裂纹扩展速率的影响。结果表明:双裂纹间距的的大小并没有对裂纹的扩展速率产生影响。     

Catalytic Activity of Ceramic Honeycombs in the Exhaust Gas Oxidation of a Waste Treatment Plant

The activity of ceramic honeycombs with varying material composition and degree of utilization is compared on a suitable model gas in a test plant. The tested honeycombs are standard products that have not been surface‐treated in any way. A propane‐air mixture was fed to the test plant and then oxidized in a high‐temperature furnace. The analysis of the conversion rate over the reaction temperature showed remarkable differences in activity. The honeycomb with the most promising results was further investigated with the exhaust gas from the drying process of a waste treatment plant. Finally, the activity of this honeycomb was assessed in a large‐scale trial in an existing running regenerative thermal oxidizer.     

High strain rate compressive response of the Cf/SiC composite

Carbon fiber reinforced ceramic owns the properties of lightweight, high fracture toughness, excellent shock resistance, and thus overcomes ceramic's brittleness. The researches on the advanced structure of astronautics, marine have exclusively evaluated the quasi-static mechanical response of carbon fiber reinforced ceramics, while few investigations are available in the open literature regarding elastodynamics. This paper reports the dynamic compressive responses of a carbon fiber reinforced silicon carbide (C_f/SiC) composite (CFCMC) tested by the material test system 801 machine (MTS) and the split Hopkinson pressure bar (SHPB). These tests were to determine the rate dependent compression response and high strain rate failure mechanism of the C_f/SiC composite in in-plane and out-plane directions. The in-plane compressive strain rates are from 0.001 to 2200?s^?1, and that of the out-plane direction are from 0.001 to 2400?s^?1. The compressive stress-strain curves show the C_f/SiC composite has a property of strain rate sensitivity in both directions while under high strain rate loadings. Its compressive stiffness, compressive stress, and corresponding strain are also strain rate sensitive. The compressive damage morphologies after high strain rate impacting show different failure modes for each loading direction. This study provides knowledge about elastodynamics of fiber-reinforced ceramics and extends their design criterion with a reliable evaluation while applying in the scenario of loading high strain rate.     

Evaluation of bull fertility in Italian Brown Swiss dairy cattle using cow field data

Dairy bull fertility is traditionally evaluated using semen production and quality traits; however, these attributes explain only part of the differences observed in fertility among bulls. Alternatively, bull fertility can be directly evaluated using cow field data. The main objective of this study was to investigate bull fertility in the Italian Brown Swiss dairy cattle population using confirmed pregnancy records. The data set included a total of 397,926 breeding records from 1,228 bulls and 129,858 lactating cows between first and fifth lactation from 2000 to 2019. We first evaluated cow pregnancy success, including factors related to the bull under evaluation, such as bull age, bull inbreeding, and AI organization, and factors associated with the cow that receives the dose of semen, including herd-year-season, cow age, parity, and milk yield. We then estimated sire conception rate using only factors related to the bull. Model predictive ability was evaluated using 10-fold cross-validation with 10 replicates. Interestingly, our analyses revealed that there is a substantial variation in conception rate among Brown Swiss bulls, with more than 20% conception rate difference between high-fertility and low-fertility bulls. We also showed that the prediction of bull fertility is feasible as our cross-validation analyses achieved predictive correlations equal to 0.30 for sire conception rate. Improving reproduction performance is one of the major challenges of the dairy industry worldwide, and for this, it is essential to have accurate predictions of service sire fertility. This study represents the foundation for the development of novel tools that will allow dairy producers, breeders, and artificial insemination companies to make enhanced management and selection decisions on Brown Swiss male fertility.